We're given the vectors

(a) Two vectors are perpendicular if their dot product is zero. For instance, 
 and
 and 
 are not perpendicular because
 are not perpendicular because

You'll find that none of these vectors taken two at a time are perpendicular to each other.
(b) Recall for any two vectors 
 and
 and 
 that
 that

where 
 is the angle between
 is the angle between 
 and
 and 
 . If these vectors are parallel, then the angle between them is 0 rad or π rad, meaning they point in the same or in opposite directions, respectively.
. If these vectors are parallel, then the angle between them is 0 rad or π rad, meaning they point in the same or in opposite directions, respectively.
We have cos(0) = 1 and cos(π) = -1, so

For instance, we know that

and we have

so 
 and
 and 
 are indeed parallel and point in opposite directions, since -11 = - √11 × √11.
 are indeed parallel and point in opposite directions, since -11 = - √11 × √11.
On the other hand, 
 and
 and 
 are not parallel, since
 are not parallel, since

and clearly 3 ≠ ±11/3.
It turns out that (a, b) is the only pair of parallel vectors.
(c) The cosine of an angle measuring between 0 and π/2 rad is positive, so you just need to check the sign of

For instance, we know 
 and
 and 
 are parallel and have an angle of π rad between them. cos(π) = -1, so this pair doesn't qualify. Meanwhile, the angle between
 are parallel and have an angle of π rad between them. cos(π) = -1, so this pair doesn't qualify. Meanwhile, the angle between 

so 
 and
 and 
 do qualify.
 do qualify.
You'd find that the pairs ((a, c), (a, d), (a, g), (c, d), (c, g), (d, g)).
(d) An angle between π/2 and π has a negative cosine. None of the vectors are perpendicular to each other, so this happens for the remaining pairs, ((a, b), (b, c), (b, d), (b, g)).