Final answer:
The oxidation number of sulfur in Na2S4O6 is +4.
Step-by-step explanation:
In the compound Na2S4O6, the oxidation number of sulfur can be calculated using the given guidelines.
- According to guideline 3, the oxidation number for H is +1.
- Using this oxidation number and the compound's formula, guideline 4 may then be used to calculate the oxidation number for sulfur.
- Assuming the usual oxidation number for oxygen (-2 per guideline 3), the oxidation number for sulfur is calculated as directed by guideline 4.
Therefore, the oxidation number of sulfur in Na2S4O6 is +4.