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Your question: During which change is heat energy absorbed
My Answer: Change of phase
More Details:
A phase change is a physical process in which a substance goes from one phase to another. Usually the change occurs when adding or removing heat at a particular temperature, known as the melting point or the boiling point of the substance.
However, If we are talking about which phase change is heat energy absorbed by a substance, then your answer would be Evaporation:
The process of converting a liquid to a gas is called evaporation. 600 cal is needed to convert 1g of water to water vapor at 0 °C or 540 cal at 100 °C.
The thermal energy absorbed by the molecules of a liquid during evaporation is used only to give them the movement needed to escape from the liquid's surface and become a gas. This energy, which is later released as heat when the vapor is liquid again, is called latent heat of vaporization.