Final answer:
To balance the half-reaction S2O3 2- (aq) → S4O6 2- (aq) in acidic solution, add water and protons (H+) to the appropriate sides of the equation.
Step-by-step explanation:
To complete and balance the half-reaction S2O3 2- (aq) → S4O6 2- (aq) in acidic solution, we need to consider the oxidation states of sulfur.
In S2O3 2-, the oxidation state of sulfur is +2, while in S4O6 2-, the oxidation state of sulfur is +6.
To balance the reaction, we can add water molecules and protons (H+) to the appropriate sides of the equation:
S2O3 2- (aq) + 2H2O (l) → S4O6 2- (aq) + 4 H+ (aq)
This equation is now balanced in terms of both atoms and charge.