Final answer:
Adding chlorine gas to the system will cause the equilibrium to shift to the left, increasing NOCl concentration and decreasing NO and Cl2 concentrations.
Step-by-step explanation:
For the equilibrium reaction 2NOCl(g) ⇌ 2NO(g) + Cl₂(g), if chlorine gas is added to the system, Le Chatelier's principle suggests that the equilibrium will shift to counteract this change by consuming the added Cl₂. Thus, the equilibrium will shift to the left, leading to an increase in the concentration of NOCl and a decrease in the concentration of NO and Cl₂ to re-establish equilibrium.