The answer is: the percent by mass of sodium is 32.4%.
The percent by mass is calculated by atomic mass of element multiply by number of that element in molecule divided by molecular mass of molecule. 
Ar(Na) = 23; the relative atomic mass of sodium atom. 
Mr(Na₂SO₄) = 2 · Ar(Na) + Ar(S) + 4 · Ar(O). 
Mr(Na₂SO₄) = 2 · 23 + 32 + 4 · 16. 
M(Na₂SO₄) = 142; relative moecular mass of sodium sulfate.
ω(Na)= 2 · Ar(Na) ÷ Mr(Na₂SO₄) · 100%. 
ω(Na) = (2 · 23 ÷ 142) · 100%. 
ω(Na) = 32.4 %.