Answer:
Decomposition of potassium chlorate yields potassium chloride and oxygen as:
2KClO 
3
 
 →2KCl+3O 
2
 
 
Thus 2 moles of potassium chlorate yields 3 moles of oxygen gas.
2 moles of potassium chlorate =2×122.5=245g of potassium chlorate
At STP, the volume occupied by 1 mol of gas =22.4 dm 
3
 
the volume occupied by three moles of a gas =3×22.4=67.2dm 
3
 
Therefore, 245g of potassium chlorate yields 67.2dm 
3
 of oxygen gas
To liberate 6.72 dm 
3
 oxygen amount of potassium chlorate required is
 = 
67.2
245
 
 ×6.72=24.5g 
Hence, 24.5 g of potassium chlorate required to liberate 6.72 dm 
3
 of oxygen at STP