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Which process would bacteria living near a heat vent on the ocean floor use to build carbon based molecules such as sugars?

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Answer is: chemosynthesis.
Difference between chemosynthesis and photosynthesis is: chemosynthesis is conversion of carbon molecules (CH₄ or CO₂) into organic matter using the oxidation of inorganic compounds (H₂, H₂S, CH₄) as a source of energy, while in photosynthesis organisms to use light energy as a source of energy.
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