Answer : The 
 are, supplementary angles.
 are, supplementary angles.
Explanation :
Supplementary angles : The two angles are supplementary angle in whcih the the sum of those two angle are 

Complementary angles : The two angles are complementary angle in whcih the the sum of those two angle are 

Vertical angles : Vertical angles are the angles that are opposite to each other when two lines intersect each other.
Congruent angle : It is defined as they have the same angles.
From the above information we conclude that,
 ,
, 
 ,
, 
 and
 and 
 are the supplementary angles.
 are the supplementary angles.
 and
 and 
 are the vertical angles.
 are the vertical angles.
Hence, the 
 are, supplementary angles.
 are, supplementary angles.