You should look to units of measure when setting up problems. when math is done correctly, the units cancel out just as numbers and variables do. 
 (miles / hr) * hr = miles 
Speed = (miles / hr)
So if the Train W is traveling at x miles/hr 
Then Train E is traveling (x+14) miles/hr
The combined distance they two trains travel is 320 miles 
2x + 2(x+14) = 320 
2x + 2x + 28 = 320 
4x + 28 = 320 
4x = 292 
x = 292/4 
x = 73 miles/hr 
remember we set x as the speed for Train W 
so Train E is going 73 + 14 = 87 miles/hr