asked 118k views
1 vote
At which temperature would a reaction with h = -92 kj/mol, s = -0.199 kj/(molk) be spontaneous?

2 Answers

5 votes

Answer: 400 K is the answer for this question

answered
User Tex
by
7.9k points
2 votes

The relationship between change in Gibb's free energy, change in enthalpy and change in entropy is:

Δ
G^(0) = Δ
H^(0) - TΔ
S^(0)

For a reaction at equilibrium, Δ
G^(0) = 0

So Δ
H^(0) - TΔ
S^(0) = 0

Δ
H^(0) = TΔ
S^(0)

-92 kJ/mol = T(-0.199kJ/(mol.K))

T = 462 K

At temperatures greater than 462 K, the value T [/tex]Δ
S^(0) would become more than Δ
H^(0), giving a negative value for Δ
G^(0) . Therefore, the reaction would become spontaneous at temperatures > 462 K

answered
User Carltonp
by
8.3k points
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