A chemical equation is said to be balanced chemical equation if it has equal number of all the constituent atoms on both side of the reaction arrow.
The balanced chemical reaction for combustion of pentane is as follows:

From the above balanced chemical equation it is clear that 1 mol of 
 reacts with 8 moles of
 reacts with 8 moles of 
 to form 5 mole of
 to form 5 mole of 
 .
.
Therefore, the mole ratio of oxygen to pentane is 8:1 here.