Answer:
1⅔ cup 
Explanation:
You need ⅔ cup of sugar for every 2 cups of flour. 
For 5 cups of flour, 
Volume of sugar = 5 cups flour × (⅔ cup sugar/2 cup flour) 
 = 5 × ⅔ × ½ Divide numerator and denominator by 2 
 = 5 × ⅓ 
 = ⁵/₃ Convert to mixed number 
 = 1⅔ cup 
Five cups of flour take 1⅔ cup of sugar.