There are 5.43 x 10²³ present in 187 grams of XeF₄
Further explanation 
The mole is the number of particles(molecules, atoms, ions) contained in a substance 
1 mol = 6.02.10²³ particles 
Can be formulated 
N=n x No 
N = number of particles 
n = mol 
No = Avogadro's = 6.02.10²³ 
Moles can also be determined from the amount of substance mass and its molar mass

mass of XeF₄ = 187 g
mol XeF₄ (MW=207,2836 g/mol) :

Number of molecules :
