Proving congruency:
CA = CA, reflexive
 m ∠DCA = m ∠BAC, alt interior ∠
m ∠BCA = m ∠DAC, alt interior ∠
triangle DCA = triangle BCA, ASA 
Supplementary angles means a pair of angles adding to 180 degrees.
180 degrees would be a straight angle.
 ∠DCA + ∠BCA = ∠DCB, not a straight angle.
Hope this helped.