The molarity of sucrose solution is 0.19 M.
The molarity of HCl is 12.8 M.
Step-by-step explanation:
a. Molarity can be found by finding its moles and volume of water in L and then dividing both(moles divided by volume in Litres).
Mass of sucrose = 318. 6 g 
Molar mass of sucrose = 342.3 g/mol
Moles = 

 = 

 = 0.93 moles 
 Mass of water = 4905 g
Density of water = 1000 g/L 
Volume = 

 = 

  = 4.905 L 
Now we can find the molarity = 

 = 

 = 0.19 M
So the molarity of sucrose solution is 0.19 M.
b. The molarity of HCl can be found as follows.
It is given that 39% HCl that means it contains 39 g of acid in 100 g of water.
Density of the solution is 1.20 g/mL, from this mass can be found as, 
 
= 1200 g 
Now we have to find out the amount of HCl in grams as,

= 468 g HCl 
Now we have to find the number of moles, 
moles = 

 = 12.8 moles 
 Molarity of HCl = 

 = 12.8 M
So the molarity of HCl is 12.8 M.