Hey there! 
C₆H₁₄ + O₂ → CO₂ + H₂O 
Balance H. 
14 on the right, 2 on the left. Add a coefficient of 7 in front of H₂O. 
C₆H₁₄ + O₂ → CO₂ + 7H₂O 
Balance C. 
6 on the left, 1 on the right. Add a coefficient of 6 in front of CO₂. 
C₆H₁₄ + O₂ → 6CO₂ + 7H₂O 
Balance O. 
2 on the left, 12 on the right. Add a coefficient of 6 in front of O₂. 
C₆H₁₄ + 6O₂ → 6CO₂ + 7H₂O 
Our final balanced equation: C₆H₁₄ + 6O₂ → 6CO₂ + 7H₂O 
Hope this helps!