Answer:
Acetic acid (
) can release only one single H+ ion . 
Therefore we can say that acetic acid has only one pKa value.
Amino acids have one -COOH( carboxylic group) group and one -NH2 (amino group) group which can both release one single H+ ion.
Step-by-step explanation:
Acetic acid (
) can release only one single H+ ion . 
Therefore we can say that acetic acid has only one pKa value.
 
Amino acids have one -COOH( carboxylic group) group and one -NH2 (amino group) group which can both release one single H+ ion.
In amino acids -
 group becomes 
 in the presence of acids.
 
in the presence of bases 
 becomes 

 
Therefore two pKa values can be observed amino acids.