The given molecule C_12 H_22 O_11 is sucrose.
Sucrose of not dissociable in water hence Vant Hoff factor is 1 
i.e
- i=1
 - molality=m=0.3
 - k=freezing point constant (As we don't need to find the perfect freezing point let's keep it constant)
 

For Sucrose

Now.
Let's check Vant Hoff factor of each compound.
- AlCl_3=4
 - CuCl_2=3
 - NaCl=2
 - C_6H_12O=1
 
Let's count Freezing point of each compound.
AlCl_3
m=0.075

CuCl_2
m=0.15

NaCl:-
m=0.3

Glucose:-
m=0.6

Hence option A is correct