Answer: Solution D has the highest concentration of all.
Step-by-step explanation:
The formula used to calculate molarity:
 .....(1)
Molarity of permanganate solution = 0.1 M
Volume of solution = 
  (Conversion factor: 
)
Putting values in equation 1, we get:

Molarity of permanganate solution = 0.01 M
Volume of solution = 

Putting values in equation 1, we get:

Molarity of permanganate solution = 2 M
Volume of solution = 

Putting values in equation 1, we get:

Molarity of permanganate solution = 2.5 M
Volume of solution = 

Putting values in equation 1, we get:

The solution having the highest number of moles will have the highest concentration for the same volume.
Thus, solution D has the highest concentration of all.