Answer:
 θ = 35.7º
Step-by-step explanation:
For this exercise we must use the law of Malus 
 I = I₀ cos² θ 
where the angle is between the two polarizers. 
 
When the unpolarized light from the sun reaches the first polarizer, only the light polarized in the direction manages to be transmitted, which is why 
 I₁ = I₀ /2 
 
this light reaches the second polarizer 
 I₂ = I₁ cos² θ 
 I₂ = I₀/2 cos² θ
 cos² θ = 2 I₂ / Io 
indicate that the transmitted light is 33% = 0.33 I₀ 
 cos² θ = 2 0.33 
 cos θ = √0.66 
 θ = cos⁻¹ 0.8124 
 θ = 35.7º