answer and explanation
we are asked to determine the number of mols of Oxygen in the sample and we can do this using the ideal gas equation
PV = nRT 
 and when we rearrange the equation to make n subject of the formula, we gent :
n = PV/RT
 = (3.21atm x 47.6L) / (0.0821 x 285K)
 = 152.796 / 23.3985
 = 6.53 mols