Answer:
D
Step-by-step explanation:
KClO3 ==> KCl + O2
 1 K 1 
 1 Cl 1
 3 O 2
There are a different amount of oxygen atoms so this equation is not balanced
KClO3 ==> 3KCl + O2
 1 K 3
 1 Cl 3
 3 O 2
None of the elements have the same number of atoms on either side of the equation therefore this equation is not balanced. 
2KClO3 ==> KCl + 3O2
 2 K 1
 2 Cl 1
 6 O 6
The number of potassium atoms and chlorine atoms is different on both sides of the equation therefore this equation is not balanced. 
2KClO3 ==> 2KCl + 3O2
 2 K 2
 2 Cl 2
 6 O 6
The number of atoms of each element are the same on both sides therefore this equation is balanced.