Answer: Sample A has 0.995 moles, this is bigger than the moles of Sample B that has 0.973 moles. 
Step by step solutions: 
1. Convert Molecules of sample A into moles: 
 1 mole of A contains 6.022x10^23 molecules 
∴ x moles A contains 5.99x10^23 molecules 
Then, moles of A = (5.99x10^23 /6.022x10^23 )molecules 
 =5.99/6.02 
 =0.995moles of A Sample 
2. Convert Mass of Sample B into moles :
Given that -
Mass = 93.5g 
Mol Mass Ammonium carbonate (NH4)2CO3= 96,09 g/mol
∴ moles B = mass /molecular mass 
 =93.5g /96.09g/mol
 =0.973 moles of sample B
3. Compare the moles of Sample A and B 
Conclusion: Sample A has 0.995 moles, this is bigger that the moles of Sample B that has 0.973 moles.