1. At STP, Volume of 1 mol of a gas occupies volume of 22.4 L
 ratio of 1 mol : 22.4
 then 4.2 mol : x .....(cross multiply ) 
 4.2 mol * 22.4 L= x mol.L 
 x = 94.08 L
Alternatively, you can say : 
1 mol = 22.4 L 
Volume of 4.2 mol = (4.2mol Ne * 22.4L )/1 mol Ne = 94.08
Option C is the correct ans