Hi 
To compare two fractions, you have to make them at same denominator. 
As we have 3 and 5 , and 15 is common to both 3 and 5 as 3*5 = 15 , I will convert both fraction in order to have fraction where 15 is denominator. 
How to do so ? well, I multiply both numerator and denomintator of -1/3 by 5 and numerator and denomintator of -2/5 by 3 
So we have : -1/3 = -1*5 / 3*5 = -5/15 
So we have :  -2/5 = -2*3 / 5*3 =  -6 / 15 
Now as both fraction have same denominator, I check which numerator is the greater. 
Remember that greater for a negative number means : which one is closest to 0. 
 If you have trouble to remember that, just imagine that numbers are on a vertical line, or like storey in a skyscrapper. ( and 0 is street floor ) 
 
If you are at storey -5 , are you above or under storey -6 ? near the ground , or deeper in basement ? 
If you are above, then number is greater. If you are under, then number is smaller. 
Well , -5 is closer to 0 than -6 , 
so -5/15 ≥ -6/15 
so -1/3 ≥ -2/5