Final answer:
Starch and cellulose both consist of glucose monomers, but differ in their glycosidic linkages; cellulose has β-1,4 linkages forming rigid structures, while starch has α-1,4 and α-1,6 linkages resulting in a helical, less rigid form.
Step-by-step explanation:
The atomic structures of starch and cellulose are different which gives them distinct physical properties. The main structural difference lies in the type of glycosidic linkages; cellulose has β-1,4 glycosidic linkages that contribute to its rigidity, allow it to form crosslinks, and create a linear chain. In contrast, starch has α-1,4 and α-1,6 glycosidic linkages, which result in a less rigid structure without the tight crosslinks present in cellulose.
Additionally, starch molecules like amylose exhibit a helical structure, which is capable of trapping iodine molecules, resulting in a dark blue color when iodine contacts starch. This structural difference is important as it affects the biochemical reactions they undergo, with enzymes that can hydrolyze starch being unable to act on cellulose, and vice versa.
While starch, found in plants, serves primarily as an energy store, cellulose is a crucial structural component of plant cell walls. The biochemical distinction between these two polymers of glucose prevents plants from breaking down their structural components when the demand for energy increases.