Answer:
The pressure of the balloon when it is fully cooled to 4.000°C is 0.994 atm (rounded to 3 significant figures).
Step-by-step explanation:
To solve this problem, we can use the Ideal Gas Law:
PV = nRT
where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin.
First, we need to convert the initial temperature from Celsius to Kelvin:
T1 = 11.2°C + 273.15 = 284.35 K
Next, we can use the given pressure, temperature, and the Ideal Gas Law to find the initial volume of the balloon:
V1 = nRT1/P1
Now, we need to find the final pressure of the balloon when it is cooled to 4.000°C. We can assume that the volume of the balloon remains constant throughout the cooling process since it is sealed.
T2 = 4.000°C + 273.15 = 277.15 K
P2 = nRT2/V1
Since the number of moles and volume of the balloon do not change, we can rewrite the above equation as:
P2/P1 = T2/T1
Solving for P2, we get:
P2 = P1(T2/T1) = 1.02 atm x (277.15 K/284.35 K) = 0.994 atm
Therefore, the pressure of the balloon when it is fully cooled to 4.000°C is 0.994 atm (rounded to 3 significant figures).