We know that the original recipe is for 6 people, and it requires 800g of pineapple, 4 egg whites, and 1/2 lemon.
If Dan uses 2 1/2 lemons instead of 1/2 lemon, that means he's using 5 times as much lemon juice. Therefore, he's likely making 5 times the original recipe.
So, for Dan's pineapple sorbet, he would need:
800g x 5 = 4000g (or 4kg) of pineapple
4 x 5 = 20 egg whites
1/2 lemon x 2.5 = 1 1/4 lemons (but since we can't really use a quarter of a lemon, we'll just say he needs 1.5 lemons)
Therefore, Dan is making pineapple sorbet for 6 x 5 = 30 people.