The correct grouping is:
F, T, T, F
Step-by-step explanation:
- The first statement is false. Although the system is not closed in the strictest sense, it can still reach equilibrium because the reactants and products are all gases and can interact with each other.
- The second statement is true. According to Le Chatelier's principle, increasing the concentration of a reactant will shift the equilibrium towards the products, in this case, CO2 and water.
- The third statement is also true. Increasing the temperature will increase the rate of the forward reaction, causing the equilibrium to shift towards the products.
- The fourth statement is false. Adding CO2 to the system will not affect the volume of methane and oxygen. It may, however, affect the equilibrium position by shifting it towards the reactants, as Le Chatelier's principle predicts that adding a product will shift the equilibrium towards the reactants.