Final answer:
Brazil is the country with the Serra do Mar mountain range, which extends from Santa Catarina to Rio de Janeiro, and includes cities such as Vitória, São Paulo, and Curitiba.
Step-by-step explanation:
The country that has the Serra do Mar range from Santa Catarina to Rio de Janeiro is Brazil. The Serra do Mar is a significant mountain range that runs along the southeastern coast of Brazil. It spans several states, including Santa Catarina, and stretches up to Rio de Janeiro, encompassing the cities of Vitória, São Paulo, Curitiba, Santos, Paranagua, and Porto Alegre.
These regions are significant not only for their mountainous landscapes but also for their economic and cultural contributions to the country. For example, Rio de Janeiro is known for its international business presence and cultural festivities, such as its famous carnival. Additionally, Brazil's south region has a history of colonization by the Portuguese and European immigration, which led to the development of industries like wine-making in areas populated by Italian immigrants and cattle raising by German settlers.