Final answer:
The most likely diagnosis for Ms. S is bipolar disorder, considering the symptoms of mania, including euphoria, decreased need for sleep, and increased energy, as well as the presence of erotomanic delusions.
Step-by-step explanation:
The most likely diagnosis at the time of admission for Ms. S, a 24-year-old woman presenting with a recent history of bizarre behavior, increased use of substances, and several psychiatric symptoms, is bipolar disorder. This diagnosis is based on her two-week history of elevated energy, decreased need for sleep, increased talkativeness, flight of ideas, distractibility, and inflated self-esteem. Furthermore, such features as the euphoric mood, presence of delusions without hallucinations, the recruitment of substances, and a hyperfocus on a particular individual (erotomanic delusions) are compatible with a manic episode. Other choices like schizophrenia are less likely due to the absence of characteristic hallucinations, negative symptoms, and a greater chronicity in symptom development, while substance-induced psychotic disorder is not typically associated with such clear manic features.