Final answer:
The higher heat of combustion indicates more energy release during combustion, making it easier to ignite the solvent, resulting in a lower flash point.
Step-by-step explanation:
The higher the heat of combustion of a solvent, the greater the amount of heat released when the solvent burns in oxygen and the easier it is to exceed the activation energy of the solvent. This results in a lower flash point. Therefore, the correct answer is a) greater, easier, lower.
Intermolecular forces
The heat of combustion is indicative of the amount of energy released during the combustion process. A higher heat of combustion means more energy is being released, which makes it easier to reach or exceed the energy barrier necessary to initiate the reaction - known as the activation energy. With a lower activation energy threshold, the solvent will ignite at a lower temperature, which is reflected in a lower flash point.