Final answer:
There are no references to characters named Ali or Emma or a place called Smoochie's in the provided text excerpts, hence an accurate answer cannot be provided.
Step-by-step explanation:
The question asks which items Ali had enough money to buy when she first accompanied Emma to Smoochie's. However, none of the provided excerpts from the texts include characters named Ali or Emma, nor do they mention a place called Smoochie's.
Therefore, it is not possible to provide an accurate answer to this question based on the given information. As this is likely a case of confusion with specific names or details from the text, I recommend reviewing the source material to locate the correct information about Ali and Emma's purchases.