Answer:
The EMF of each battery is 6 volts and the EMF of two batteries connected in series is 12 volts. 
Step-by-step explanation:
According to the Kirchhoff's Voltage Law, net voltage of a closed circuit must be zero. That is:
 (1)
Where 
 is the voltage of the i-th component of the closed circuit, measured in volts. Please notice that voltage for a power generating element (i.e. EMF) is less than zero and for a power consuming element is greater than zero (i.e. Batteries being charged by the EMF). In addition, if n-elements are connected in series, then the equivalent voltage is:
 (2)
Let consider that closed system is formed by two batteries connected in series and an EMF, by (1) and (2) we have that:

 (3)
If we know that 
, then the EMF of the battery is:

The EMF of each battery is 6 volts and the EMF of two batteries connected in series is 12 volts.