Final answer:
70.7345 mL. of a 4.69% AgNO3 solution is required to react exactly with 9.9 mL of 14.01% Na2SO4 solution.
Step-by-step explanation:
To calculate the volume of a 4.69% AgNO3 solution needed to react with 9.9 mL of 14.01% Na2SO4 solution, you need to write a balanced chemical equation and perform stoichiometric calculations. We are dealing with a precipitation reaction where AgNO3 reacts with Na2SO4 to form Ag2SO4 and NaNO3:
2AgNO3(aq) + Na2SO4(aq) → Ag2SO4(s) + 2NaNO3(aq)
The reaction ratio for AgNO3 to Na2SO4 is 2:1. To find the moles of Na2SO4, you use the concentration and the volume of Na2SO4 solution:
Moles of Na2SO4 = (14.01% weight/volume of Na2SO4) × (9.9 mL Na2SO4 solution) / (Molar mass of Na2SO4)
Now, since the reaction ratio is 2:1, we need twice as many moles of AgNO3 to react with Na2SO4:
Moles of AgNO3 required = 2 × Moles of Na2SO4
To find the volume of AgNO3 solution required, you divide the moles of AgNO3 by the concentration of AgNO3:
Volume of AgNO3 solution = Moles of AgNO3 / (4.69% weight/volume of AgNO3)
Converting the 4.69% w/v solution to molarity and then calculating the volume gives you approximately 70.7345 mL.