Do you want a general solution or from 0 <= x < 2pi? 
 tan^2(2x) - 1 = 0 
 tan^2(2x) = 1 
 Take the square root of both sides, 
 tan(2x) = +/- 1 
 Two equations: 
 tan(2x) = 1 
 tan(2x) = -1 
 Solve each equation. 
 tan(2x) = 1, 2x = {pi/4, 5pi/4, 9pi/4, 13pi/4}, 
 x = { pi/8, 5pi/8, 9pi/8, 13pi/8 } 
 tan(2x) = -1, 2x = { 3pi/4, 7pi/4, 11pi/4, 15pi/4 }, 
 x = { 3pi/8, 7pi/8, 11pi/8, 15pi/8} 
 So for solutions within [0, 2pi), 
 x = {pi/8, 3pi/8, 5pi/8, 7pi/8, 9pi/8, 11pi/8, 13pi/8, 15pi/8 }