Question

Morphine has the formula c17h19no3. it is a base and accepts one proton per molecule. it is isolated from opium. a 0.685 −g sample of opium is found to require 8.91 ml of a 1.16×10−2 m solution of sulfuric acid for neutralization. part a assuming that morphine is the only acid or base present in opium, calculate the percent morphine in the sample of opium.

Answer 1

2 C₁₇H₁₉NO₃ + H₂SO₄ → Product
Moles of H₂SO₄ = M x V(liters) = 0.0116 x 8.91/1000 = 1.033 x 10⁻⁴ mole
moles of morphine = 2 x moles of H₂SO₄ = 2.066 x 10⁻⁴
Mass of morphine = moles x molar mass of morphine = 2.066 x 10⁻⁴ x 285.34
= 0.059 g
percent morphine =
`(mass of morphine)/(mass of opium) x 100`
=
`(0.059)/(0.685) x 100` = 8.6 %