asked 209k views
1 vote
Look up the boiling points of anisole and d-limonene. which one do you expect to elute first in gas chromotograpjhy

1 Answer

5 votes
The primary factor that determines the elution order of compounds during gas chromatography, is the boiling point of the compounds. The lower the boiling point of a substance, the shorter retention time the substance will have. The retention time is the time it takes for the substance to be injected into the GC and reach the detector.

A lower boiling compound will elute faster (shorter retention time) than a higher boiling compound. The reason for this is the mobile phase of GC is a gas while the stationary phase is a liquid. Therefore, the more time a compound spends in the mobile phase, the faster it will elute.

The boiling point of anisole and d-limonene are 153.8 °C and 176 °C, respectively. Therefore, anisole will have a shorter retention time since it has the lower boiling point.
answered
User Greenisus
by
8.0k points
Welcome to Qamnty — a place to ask, share, and grow together. Join our community and get real answers from real people.