You must use 2.50 mL of the concentrated solution to make 10.0 mL of the dilute solution. 
We can use the dilution formula 
V_1C_1 = V_2C_2 
where 
V represents the volumes and 
C represents the concentrations 
We can rearrange the formula to get 
V_2 = V_1 × (C_1/C_2) 
V_1 = 10.0 mL; C_1 = 5.00 g/100. mL 
V_2 = ?; ____C_2 = 20.0 g/100. mL 
∴ V_2 = 10.0 mL × [(5.00 g/100. mL)/(20.0 g/100. mL)] = 10.0 mL × 0.250
= 2.50 mL