The coin we choose is equally likely to be fair or unfair, since the ratio of fair to unfair coins is 2:2 = 1:1.
So, 50% of the times we pick a fair coin, which lands on heads with probability 50%.
The other 50% of the times we pick an unfair coin, which lands on heads with probability 90%.
Since these two events are mutually exclusive (a coin is either fair or unfair), the probability of having the coin to land on heads is
