We can use the heat equation,
Q = mcΔT 
Where Q is the amount of energy transferred (J), m is the mass of the substance (kg), c is the specific heat (J g⁻¹ °C⁻¹) and ΔT is the temperature difference (°C).
  
 Q = ?
 m = 100.0 g
 c = 4.18 J/g°c
ΔT = (37 - 4) °C = 33 °C
  
 By applying the formula,
Q = 100.0 g x 4.18 J/g °C x 33°C
Q = 13794 J
Hence, needed energy is 13794 J.