Answer:
mass of NaHCO₃ = 0.126 g 
Step-by-step explanation:
balanced chemical equation 
H₃C₆H₅O₇(aq) + 3 NaHCO₃(aq) → 3 H₂O(l) + 3 CO₂(g) + Na₃C₆H₅O₇(aq).
given data  
moles of citric acid = 1 mol 
mas of citric acid = 100 mg
mas of citric acid = 0.1 g
moles of sodium bicarbonate = 3 mol 
mass of sodium bicarbonate = ? 
Solution 
1st we will find out the mole ratio of H₃C₆H₅O₇ and NaHCO₃ from balanced chemical equation 
H₃C₆H₅O₇ : NaHCO₃ 
 1 : 3 
Now we find out number of moles of citric acid 
 moles = mass / molar mass 
 moles = 0.1 g / 192.124 g/mol 
 moles = 0.0005 mol 
now we find out moles (x) of sodium bicarbonate needed for 0.0005 mol of citric acid 
from the balanced chemical equation the mole ratios are: 
 1 : 3
0.0005 mol : x 
Cross multiply these ratios 
 3 × 0.0005 = 1x 
 0.0015 = 1 x 
 x = 0.0015 mol 
Now we will find out the mass of sodium bicarbonate
  mass = moles × molar mass 
 mass of NaHCO₃ = 0.0015 mol × 84.007 g/mol
 mass of NaHCO₃ = 0.126 g