Answer :
(a) The final pressure will be 38.73 psi
(b) The initial pressure will be 26.44 psi
Explanation :
(a) Gay-Lussac's Law : It is defined as the pressure of the gas is directly proportional to the temperature of the gas at constant volume and number of moles.

or,

where,
= initial pressure of gas = 32 psi
= final pressure of gas = ?
= initial temperature of gas =

= final temperature of gas =

Now put all the given values in the above equation, we get:


Thus, the final pressure will be 38.73 psi
(b) Now we have to calculate the initial air pressure should be put in the tire.

where,
= initial pressure of gas = ?
= final pressure of gas = 32 psi
= initial temperature of gas =

= final temperature of gas =

Now put all the given values in the above equation, we get:


Thus, the initial pressure will be 26.44 psi